Plasma electrolytic oxidation (PEO) is a technique used to create oxide-ceramic coatings on lightweight metals, such as aluminium, magnesium, and titanium. PEO is known for producing coatings with high corrosion resistance and strong adhesion to the substrate. The process involves generating short-lived microdischarges on the material surface through anodic dielectric breakdown in a conductive aqueous solution. To investigate single microdischarges during PEO, a single microdischarge setup was developed, where the active anode surface is reduced to the tip of a wire with a diameter of 1 mm. In this work the focus is on the effect of electrolyte concentration, anode material, and electrical parameters on the microdischarges. The electrolyte is composed of distilled water with varying concentrations of potassium hydroxide (0.5 - 4 g/l). High-speed optical measurements are conducted to gain insights into the formation and temporal evolution of individual microdischarges and the induced gas bubble formation. Optical emission spectroscopy is used to estimate surface and electron temperatures by fitting Bremsstrahlung and Planck’s law to the continuum spectrum of the microdischarges. To evaluate the impact of the microdischarges on coating morphology, the resulting oxide layers on the metal tips are analysed using scanning electron microscopy. The study demonstrates that microdischarge behaviour is significantly influenced by the substrate material, treatment time, and electrolyte concentration, all of which impact the coating morphology. Under the conditions studied in this work, aluminium exhibits longer microdischarge and bubble lifetimes, with fewer cracks on the top layer of the coating, whereas titanium showed faster, shorter-lived bubbles due to more rapid microdischarge events.